A thermostatic valve control structure mainly has an axial movement element movable axially to control opening size of a hot water inlet and a cold water inlet. The axial movement element has a ceramic layer which has a smooth surface to reduce friction with a sealing ring. The ceramic layer provides advantages of resisting acid and alkali, less likely to accumulate water dregs, simpler structure and longer life span. Thus the total life span and durability of the thermostatic valve control structure can be enhanced.