Invention Grant
US08436217B2 Integrated process to co-produce 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene
有权
共同生产1,1,1,3,3-五氟丙烷,反式-1-氯-3,3,3-三氟丙烯和反式-1,3,3,3-四氟丙烯的综合方法
- Patent Title: Integrated process to co-produce 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene
- Patent Title (中): 共同生产1,1,1,3,3-五氟丙烷,反式-1-氯-3,3,3-三氟丙烯和反式-1,3,3,3-四氟丙烯的综合方法
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Application No.: US13093007Application Date: 2011-04-25
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Publication No.: US08436217B2Publication Date: 2013-05-07
- Inventor: Haiyou Wang , Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
- Applicant: Haiyou Wang , Daniel C. Merkel , Konstantin A. Pokrovski , Hsueh Sung Tung , Ian Shankland
- Applicant Address: US NJ Morristown
- Assignee: Honeywell International Inc.
- Current Assignee: Honeywell International Inc.
- Current Assignee Address: US NJ Morristown
- Agent Bruce O. Bradford
- Main IPC: C07C17/25
- IPC: C07C17/25 ; C07C19/08 ; C07C21/18 ; C07C23/00 ; C07C25/00 ; C07C17/00

Abstract:
Disclosed is a fully integrated process for making 1,1,1,3,3-pentafluoropropane (HFC-245fa), trans-1-chloro-3,3,3-trifluoropropene (HCFO-1233zd(E)), and trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)). The chemistry involves (a) the reaction of 1,1,1,3,3-pentachloropropane (HCC-240fa), or a derivative thereof selected from 1,1,3,3-tetrachloropropene and 1,3,3,3-tetrachloropropene, with anhydrous HF in excess in the presence of a catalyst in a liquid-phase reactor in such a way as to co-produce HCFO-1233zd, HFO-1234ze, HCFC-244fa (3-chloro-1,1,1,3-tetrafluoropropane), and HFC-245fa in a first reactor; (b) the reaction of HCFO-1233zd and HFO-1234ze with HCl in excess in the presence of a catalyst in a second reactor to convert these two olefins into HCFC-243fa and HCFC-244fa, respectively; (c) the reaction of HCFC-243fa and HCFC-244fa over a dehydrochlorination catalyst or in a caustic solution in a third reactor to form HCFO-1233zd and HFO-1234ze; and (d) the reaction of HCFO-1233zd(Z) and HFO-1234ze(Z) in the presence of a catalyst in a fourth reactor to form trans-1233zd and trans-1234ze, respectively.
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