A pair scheduling medium access control method used in a wireless network, comprises the steps of: checking, by a receiving node, whether a transmitting node has data packets to be subsequently sent, according to data packets received from the transmitting node; when the transmitting node has no data packets to be subsequently sent, checking whether the receiving node has data packets to be sent to the transmitting node or not; if the receiving node has data packets to be sent to the transmitting node, then adding a time period required for sending the data packets of the receiving node into an acknowledgement packet to be sent to the transmitting node; after the receiving node receives a Clear to Send packet sent from the transmitting node, sending the data packets in the receiving node to the transmitting node.