A light guide module capable of illuminating and being applied in a device for decoration is provided. The light guide module includes a reflective layer, a light guide with a plurality of diffusing particles, and a light source. The light guide has a side surface, a reflective surface and a light-exiting surface, thereby allowing a light from the light source to enter and reflect and exit the light guide respectively. The reflective layer is disposed on the reflective surface of the light guide for reflecting the light to the light-exiting surface. The light guide forms a portion of an outer surface of the device.