Invention Grant
US08460770B2 In situ moisture generation and use of polyfunctional alcohols for crosslinking of silane-functionalized resins 有权
用于交联硅烷官能化树脂的多官能醇的原位水分产生和使用

In situ moisture generation and use of polyfunctional alcohols for crosslinking of silane-functionalized resins
Abstract:
Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.
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