Invention Grant
- Patent Title: In situ moisture generation and use of polyfunctional alcohols for crosslinking of silane-functionalized resins
- Patent Title (中): 用于交联硅烷官能化树脂的多官能醇的原位水分产生和使用
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Application No.: US12740838Application Date: 2008-10-13
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Publication No.: US08460770B2Publication Date: 2013-06-11
- Inventor: Bharat I. Chaudhary , Jeffrey M. Cogen , Saurav S. Sengupta
- Applicant: Bharat I. Chaudhary , Jeffrey M. Cogen , Saurav S. Sengupta
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Agency: Whyte Hirschboeck Dudek SC
- International Application: PCT/US2008/079724 WO 20081013
- International Announcement: WO2009/058545 WO 20090507
- Main IPC: B32B1/02
- IPC: B32B1/02 ; B32B1/08 ; C08F8/00 ; C08F273/00 ; C08F130/08 ; C08G77/442

Abstract:
Polymer compositions comprise a (i) silane-functionalized polymer, e.g., a polyethylene grafted with vinyl triethoxy silane, (H) polyfunctional alcohol e.g., α,α,α′,α′˜tetramethyl-I,3-benzenediethanol and, optionally, (iii) acid, e.g., an alkylated aryl disulfonic acid. The use of polyfunctional alcohols in the absence of a strong acid yields a light-crosslinking of the silane-functionalized polymer and this, in turn, provides a polymer melt with improved extensional properties such as elongational viscosity and melt strength. The use of a polyfunctional alcohol in combination with a blocked strong acid provides a slow rate of crosslinking during melt processing and a high degree of ultimate crosslinking after the polymer composition has been shaped or molded.
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