A fueled cell system comprising: an anode compartment comprising a compound having the formula R1R2N—NR3R4, a salt, a hydrate or a solvate thereof, as fuel, and a catalyst layer which comprises copper or a copper alloy; a cathode compartment comprising an oxidant; and a separator interposed between said cathode and said anode compartments, wherein each of R1-R4 is independently selected from the group consisting of hydrogen, alkyl, alkenyl, alkynyl, heteroalicyclic, alkoxy, carboxy, ketone, amide, hydrazide and amine, provided that at least one of R1-R4 is hydrogen.