A polymerizable mixture for ink jetting, having liquid crystalline phases comprising the following components:a) 50-80 wt % mono-functional LCP's,b) 10-50 wt % of a higher functional LCP's,f) 0.01-5 wt % initiators, preferably below 1%g) 0.01-5 wt % inhibitors, preferably below 1%h) 0-20 wt % additives, preferably below 10 wt %,with the provision that the total amount of the components is 100 wt %, characterized in that the polymerizable mixtures has a viscosity smaller than 0.015 Pa s at 100° C. and yet remaining thermally stable.