An outer ring and an inner ring of a rolling bearing are constituted of steel containing 0.77 to 0.85% of carbon, 0.01 to 0.25% of silicon, 0.01 to 0.35% of manganese, 0.01 to 0.15% of nickel, 3.75 to 4.25% of chromium, 4 to 4.5% of molybdenum and 0.9 to 1.1% of vanadium with the rest consisting of iron and impurities, a nitrogen-enriched layer having a nitrogen concentration of at least 0.05 mass % is formed on a region including a rolling surface, and the total of a carbon concentration and the nitrogen concentration in the nitrogen-enriched layer is at least 0.82 mass % and not more than 1.9 mass %. A DLC coating layer is arranged on a region including an outer ring contact surface.