This invention provides a thin film vaporizer. The vaporizer includes a primary body having an inlet, an outlet, and an internal surface therebetween. The inlet, outlet and internal surface defining a gas passage between the inlet and the outlet. A first liquid provider is disposed proximate to the inlet and structured and arranged to provide liquid flow upon at least a portion of the internal surface. A first vaporizing zone is provided downstream from the first liquid provider and structured and arranged to provide wetting of the provided liquid flow upon at least a portion of the internal surface. The first vaporizing zone is further structured and arranged with the gas passage to permit vaporizing of the liquid and mixing with a first gas received from the inlet about contemporaneously. A heat source is thermally coupled to the first vaporization so as to apply heat by conduction, convection, radiation and or combinations thereof. An associated method of use and fuel cell incorporating the thin film vaporizer are also provided.