Invention Grant
US08497341B2 Transparent thermoplastic polyurethanes having low haze and good processability, methods of making the same, and uses therefor 有权
具有低雾度和良好加工性的透明热塑性聚氨酯,其制备方法及其用途

Transparent thermoplastic polyurethanes having low haze and good processability, methods of making the same, and uses therefor
Abstract:
Light-stable, thermoplastic polyurethanes with good processability and having an ASTM D-1003 haze value of less than 10%, the polyurethane prepared by a process comprising: reacting: (a) a diisocyanate component comprising 1,6-hexamethylene diisocyanate; (b) a chain extension component consisting of (b1) 1,4-di(β-hydroxyethyl)hydroquinone and (b2) at least one chain extender selected from the group consisting of diols having a 2 or 3 carbon atom chain length between the two OH groups, in a molar ratio of chain extender (b1) to chain extender (b2) of 10:1 to 1:4; and (c) at least one polyol component having a number average molecular weight of 450 to 10000 g/mol, and an average number of Zerewitinoff-active hydrogen atoms of at least 1.8 to at most 3.0; wherein the ratio of isocyanate groups in component (a) to isocyanate-reactive groups in components (b) and (c) is 0.9:1 to 1.1:1.
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