Invention Grant
US08497344B2 Process for making DAPBI-containing aramid crumbs 有权
制备含有DAPBI的芳纶面包屑的方法

  • Patent Title: Process for making DAPBI-containing aramid crumbs
  • Patent Title (中): 制备含有DAPBI的芳纶面包屑的方法
  • Application No.: US10580018
    Application Date: 2004-11-11
  • Publication No.: US08497344B2
    Publication Date: 2013-07-30
  • Inventor: Johannes Bos
  • Applicant: Johannes Bos
  • Applicant Address: NL Arnhem
  • Assignee: Teijin Aramid B.V.
  • Current Assignee: Teijin Aramid B.V.
  • Current Assignee Address: NL Arnhem
  • Agency: Oliff & Berridge, PLC
  • Priority: EP03026710 20031121
  • International Application: PCT/EP2004/012760 WO 20041111
  • International Announcement: WO2005/054337 WO 20050616
  • Main IPC: C08G69/08
  • IPC: C08G69/08
Process for making DAPBI-containing aramid crumbs
Abstract:
A method for obtaining a composition of an aromatic polyamide containing para-phenylene terephthalamide and 2-(p-phenylene)benzimidazole terephthalamide units, the method including copolymerizing: i) a mole % of para phenylenediamine; ii) b mole % of 5(6)-amino-2-(p-aminophenyl)benzimidazole; and iii) 90-110 mole % of terephthaloyl dichloride in a mixture of N-methyl pyrrolidone and containing c wt. % of calcium chloride, wherein c is within the range from 1 to 20, and wherein the ratio a:b ranges from 1:20 to 20:1, a+b is 100 mole %, and i), ii), and iii) together comprise 1-20 wt. % of the mixture, wherein the product b·c is at least 50 and less than 215 and that the composition is a crumb with a relative viscosity ηrel of at least 4, wherein the crumb is defined as non-sticky particles at least 95% of which having an average diameter of 0.7-15 mm.
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