Parallel Processing Communication Accelerator (PPCA) systems and methods for enhancing performance of a Parallel Processing Environment (PPE). In an embodiment, a Message Passing Interface (MPI) devolver enabled PPCA is in communication with the PPE and a host node. The host node executes at least a parallel processing application and an MPI process. The MPI devolver communicates with the MPI process and the PPE to improve the performance of the PPE by offloading MPI process functionality to the PPCA. Offloading MPI processing to the PPCA frees the host node for other processing tasks, for example, executing the parallel processing application, thereby improving the performance of the PPE.