Invention Grant
- Patent Title: Method of carbon chain extension using novel aldol reaction
- Patent Title (中): 使用新型醛醇反应的碳链延伸方法
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Application No.: US13556484Application Date: 2012-07-24
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Publication No.: US08507700B2Publication Date: 2013-08-13
- Inventor: Louis A. Silks , John C. Gordon , Ruilan Wu , Susan Kloek Hanson
- Applicant: Louis A. Silks , John C. Gordon , Ruilan Wu , Susan Kloek Hanson
- Applicant Address: US NM Los Alamos
- Assignee: Los Alamos National Security, LLC
- Current Assignee: Los Alamos National Security, LLC
- Current Assignee Address: US NM Los Alamos
- Agency: Woodcock Washburn, LLP
- Main IPC: C07D307/12
- IPC: C07D307/12 ; C10L1/04

Abstract:
Method of producing C8-C15 hydrocarbons comprising providing a ketone starting material; providing an aldol starting material comprising hydroxymethylfurfural; mixing the ketone starting material and the aldol starting material in a reaction in the presence of a proline-containing catalyst selected from the group consisting of Zn(Pro)2, Yb(Pro)2, and combinations thereof, or a catalyst having one of the structures (I), (II) or (III), and in the presence of a solvent, wherein the solvent comprises water and is substantially free of organic solvents, where (I), (II) and (III) respectively are: where R1 is a C1-C6 alkyl moiety, X=(OH) and n=2. In (III), X may be CH2, sulfur or selenium, M may be Zn, Mg, or a lanthanide, and R1 and R2 each independently may be a methyl, ethyl, phenyl moiety.
Public/Granted literature
- US20120289719A1 Method Of Carbon Chain Extension Using Novel Aldol Reaction Public/Granted day:2012-11-15
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