Invention Grant
- Patent Title: Process for preparing acrylic acid from ethanol and formaldehyde
- Patent Title (中): 从乙醇和甲醛制备丙烯酸的方法
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Application No.: US13232380Application Date: 2011-09-14
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Publication No.: US08507721B2Publication Date: 2013-08-13
- Inventor: Stefanie Herzog , Stefan Altwasser , Markus Ottenbacher , Frank Huetten , Annebart Engbert Wentink , Alexander Schaefer
- Applicant: Stefanie Herzog , Stefan Altwasser , Markus Ottenbacher , Frank Huetten , Annebart Engbert Wentink , Alexander Schaefer
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- Priority: DE102010040923 20100916
- Main IPC: C07B35/00
- IPC: C07B35/00

Abstract:
A process for preparing acrylic acid from ethanol and formaldehyde, in which, in a reaction zone A, the ethanol is partially oxidized to acetic acid in a heterogeneously catalyzed gas phase reaction, the product gas mixture A obtained and a formaldehyde source are used to obtain a reaction gas input mixture B which comprises acetic acid and formaldehyde and has the acetic acid in excess over the formaldehyde, and the formaldehyde present in reaction gas input mixture B is aldol-condensed with acetic acid present in reaction gas input mixture B to acrylic acid under heterogeneous catalysis in a reaction zone B, and unconverted acetic acid still present along-side the acrylic acid target product in the product gas mixture B obtained is removed therefrom, and the acetic acid removed is recycled into the production of reaction gas input mixture B.
Public/Granted literature
- US20120071687A1 PROCESS FOR PREPARING ACRYLIC ACID FROM ETHANOL AND FORMALDEHYDE Public/Granted day:2012-03-22
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