Invention Grant
- Patent Title: Process for the selective oxidation of hydrogen sulphide
- Patent Title (中): 硫化氢选择性氧化的方法
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Application No.: US13131130Application Date: 2009-11-26
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Publication No.: US08524189B2Publication Date: 2013-09-03
- Inventor: Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
- Applicant: Arnab Chatterjee , Carolus Matthias Anna Maria Mesters , Ronald Jan Schoonebeek
- Applicant Address: US TX Houston
- Assignee: Shell Oil Company
- Current Assignee: Shell Oil Company
- Current Assignee Address: US TX Houston
- Agent Charles W. Stewart
- Priority: EP08170251 20081128; EP08170291 20081128
- International Application: PCT/EP2009/065933 WO 20091126
- International Announcement: WO2010/060970 WO 20100603
- Main IPC: C01B17/04
- IPC: C01B17/04 ; C10L3/10

Abstract:
The present invention provides a process for the selective oxidation of hydrogen sulphide contained in a hydrogen sulphide-containing hydrocarbon feed gas to elemental sulphur. The hydrogen sulphide-containing hydrocarbon feed gas and a sulphur dioxide-containing gas are supplied to a reaction zone containing a TiO2-comprising catalyst, wherein elemental sulphur and a gaseous stream depleted in hydrogen sulphide are formed. The gas feeds are contacted with the TiO2 containing catalyst at elevated pressure and at a temperature in the range of from 120 and below 160 ° C., under such conditions that the elemental sulphur formed is essentially in liquid form. At least part of the sulphur dioxide-containing gas is obtained by combusting elemental sulphur to obtain a gaseous mixture of sulphur dioxide and nitrogen and then concentrating the gaseous mixture to provide the sulphur dioxide-containing gas.
Public/Granted literature
- US20110274604A1 PROCESS FOR THE SELECTIVE OXIDATION OF HYDROGEN SULPHIDE Public/Granted day:2011-11-10
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