Invention Grant
- Patent Title: Process for continuous modification of dihydrate gypsum and modified dihydrate gypsum obtained by the process
- Patent Title (中): 通过该方法获得的二水石膏和改性二水石膏的连续改性方法
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Application No.: US13055891Application Date: 2009-07-31
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Publication No.: US08529863B2Publication Date: 2013-09-10
- Inventor: Itaru Yokoyama , Kouji Katsumoto , Yasuo Kawamura
- Applicant: Itaru Yokoyama , Kouji Katsumoto , Yasuo Kawamura
- Applicant Address: JP Tokyo
- Assignee: Yoshino Gypsum Co., Ltd.
- Current Assignee: Yoshino Gypsum Co., Ltd.
- Current Assignee Address: JP Tokyo
- Agency: Hamre, Schumann, Mueller & Larson, P.C.
- Priority: JP2008-197920 20080731
- International Application: PCT/JP2009/063666 WO 20090731
- International Announcement: WO2010/013807 WO 20100204
- Main IPC: C01F11/46
- IPC: C01F11/46

Abstract:
Disclosed is a process for the continuous modification of dihydrate gypsum. The process includes a hemihydration step of calcining the dihydrate gypsum as a raw material into hemihydrate gypsum and a recrystallization step of hydrating and recrystallizing the hemihydrate gypsum in an aqueous slurry to convert the hemihydrate gypsum into modified dihydrate gypsum of a crystalline form different from the dihydrate gypsum as the raw material. In the recrystallization step, the aqueous slurry in a recrystallization reaction tank is maintained at a constant temperature under stirring such that the aqueous slurry becomes uniform, and a feed rate of the hemihydrate gypsum to the recrystallization reaction tank and a discharge rate of the recrystallized and modified dihydrate gypsum from the recrystallization reaction tank are controlled such that the feed rate and the discharge rate become substantially equal to each other, whereby the feeding of the hemihydrate gypsum and the discharging of the recrystallized and modified dihydrate gypsum are conducted continuously or intermittently. According to the process, dihydrate gypsum as a starting raw material can be converted into high-purity, modified dihydrate gypsum of large crystals by recrystallizing the starting dihydrate gypsum after it is once calcined into hemihydrate gypsum although such modified dihydrate gypsum is not available in general.
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