Invention Grant
- Patent Title: Palladium catalyst and process for production of bisaryl compound using same
- Patent Title (中): 钯催化剂及其制备方法
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Application No.: US13510524Application Date: 2010-11-11
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Publication No.: US08541624B2Publication Date: 2013-09-24
- Inventor: Hisahiro Hagiwara , Norio Tsubokawa
- Applicant: Hisahiro Hagiwara , Norio Tsubokawa
- Applicant Address: JP Niigata
- Assignee: Niigata University
- Current Assignee: Niigata University
- Current Assignee Address: JP Niigata
- Agency: Duane Morris LLP
- Agent J. Rodman Steele, Jr.; Gregory M. Lefkowitz
- Priority: JP2009-265484 20091120
- International Application: PCT/JP2010/070101 WO 20101111
- International Announcement: WO2011/062109 WO 20110526
- Main IPC: C07C45/68
- IPC: C07C45/68 ; C07C1/26 ; C07C1/32

Abstract:
Disclosed are: a novel palladium catalyst which does not undergo leakage, can be recycled, does not require the use of any phosphorus-containing ligand, and has a high catalytic activity; and a process for producing a novel bisaryl compound using the palladium catalyst. In the production of a bisaryl compound by reacting an aromatic halide with an aromatic boronic acid in the presence of a palladium catalyst and a base, the palladium catalyst comprises a dendrimer containing a silica particle as a core and a palladium compound dissolved in an ionic liquid and supported on the dendrimer.
Public/Granted literature
- US20120232310A1 PALLADIUM CATALYST AND PROCESS FOR PRODUCTION OF BISARYL COMPOUND USING SAME Public/Granted day:2012-09-13
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