An unlocking method of a touch screen and an electric device with camera function thereof are disclosed. A camera module is used for capturing a plurality of images. A touch screen shows an application function icon, a shooting mode icon, an activate area and a slide path connecting the icons and the activate area while the touch screen is locked. A processing module is electrically connected with the camera module and the touch screen. While detecting that the application function icon or the shooting mode icon is dragged to the activate area through the slide path, the processing module transmits an unlocking signal to the touch screen. The touch screen unlocks according to the unlocking signal and shows a screen of application function operation or a screen of camera function. Therefore, users would feel more convenient than before while using an electric device with camera function.