Invention Grant
- Patent Title: ZSM-5, its preparation and use in ethylbenzene dealkylation
- Patent Title (中): ZSM-5,其制备和用于乙苯脱烷基化
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Application No.: US12677009Application Date: 2008-09-10
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Publication No.: US08574542B2Publication Date: 2013-11-05
- Inventor: László Domokos , Ralph Haswell , Hong-Xin Li
- Applicant: László Domokos , Ralph Haswell , Hong-Xin Li
- Applicant Address: US TX Houston
- Assignee: Shell Oil Company
- Current Assignee: Shell Oil Company
- Current Assignee Address: US TX Houston
- Agent Charles W. Stewart
- International Application: PCT/EP2008/061967 WO 20080910
- International Announcement: WO2009/034093 WO 20090319
- Main IPC: C01B39/40
- IPC: C01B39/40 ; C07C4/18 ; B01J29/44 ; B01J29/40

Abstract:
A new configuration of ZSM-5 is provided whereby the crystals have a higher average silica to alumina ratio at the edges of each crystallite than in the center as determined from a narrow slit line scan profile obtained from SEM/EDX or TEM/EDX elemental analysis. Such ZSM-5 crystals are obtained by a preparation process using L-tartaric acid. The new configuration ZSM-5 provides significantly reduced xylene losses in ethylbenzene dealkylation, especially when combined with silica as binder, and one or more hydrogenation metals selected from platinum, tin, lead, silver, copper, and nickel. Further advantages are found if used in combination with a small crystal size ZSM-5.
Public/Granted literature
- US20100217057A1 ZSM-5, ITS PREPARATION AND USE IN ETHYLBENZENE DEALKYLATION Public/Granted day:2010-08-26
Information query
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