A thermal management system includes an enable module, a status module and a temperature control module. The enable module enables generation of ammonia for use in selective catalytic reduction (SCR) catalysts of an exhaust system during a passive SCR mode. The status module determines whether the exhaust system is operating in a passive SCR mode and generates a passive SCR active signal. The passive SCR mode includes operating an engine with rich air/fuel ratios. The temperature control module activates electrical heating of an oxidation catalyst based on the passive SCR active signal and a temperature of the oxidation catalyst.