Invention Grant
- Patent Title: Olefin functionalization by metathesis reaction
- Patent Title (中): 烯烃通过复分解反应进行功能化
-
Application No.: US13624041Application Date: 2012-09-21
-
Publication No.: US08623962B2Publication Date: 2014-01-07
- Inventor: John R. Hagadorn , Matthew W. Holtcamp , Andrew G. Narvaez, Jr. , Donna J. Crowther , Patrick Brant
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- Agent Kevin M. Faulkner; Catherine L. Bell
- Main IPC: C08F255/00
- IPC: C08F255/00 ; C08F255/02 ; C08F210/06 ; C08F110/06

Abstract:
This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)−83), when 70 to 90 mol % ethylene is present in the co-oligomer. This invention also relates to a process to functionalize propylene homo-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum.
Public/Granted literature
- US20130030126A1 Olefin Functionalization By Metathesis Reaction Public/Granted day:2013-01-31
Information query