A process for electrolyzing a material to change at least a portion of the material from a first chemical state to a second chemical state includes placing a known quantity of a first substance into either a mixing chamber or an electrolysis chamber of an integrated electrochemical reactor, placing a known quantity of a second substance into the other chamber free of the first substance; sealing an opening to isolate an internal volume within the reactor; rotating the reactor to form a mixture, rotating the reactor again such that the mixture is transferred to the electrolysis chamber; electrolyzing the mixture in the electrolysis chamber to change at least a portion of the mixture from the first chemical state to the second chemical state; and analyzing the first substance, or analyzing the second substance, or analyzing the first chemical state, or analyzing the second chemical state, or any analytical combinations thereof.