Invention Grant
- Patent Title: Phosphine-oxide catalyzed process of production of hydrogen from silylated derivatives as hydrogen carrier
- Patent Title (中): 氧化膦催化从甲硅烷基化衍生物作氢载体生产氢的方法
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Application No.: US13578860Application Date: 2011-02-15
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Publication No.: US08642003B2Publication Date: 2014-02-04
- Inventor: Jean-Michel Brunel
- Applicant: Jean-Michel Brunel
- Applicant Address: FR Marseilles FR Paris
- Assignee: Universite d'Aix-Marseille,Centre National de la Recherche Scientifique (C.N.R.S.)
- Current Assignee: Universite d'Aix-Marseille,Centre National de la Recherche Scientifique (C.N.R.S.)
- Current Assignee Address: FR Marseilles FR Paris
- Agency: Thompson Coburn LLP
- International Application: PCT/EP2011/052192 WO 20110215
- International Announcement: WO2011/098614 WO 20110818
- Main IPC: C01B3/22
- IPC: C01B3/22

Abstract:
The invention relates to a method for producing hydrogen comprising the steps of: i) contacting a compound (C) comprising one or more groups Si—H with a phosphorous based catalyst in the presence of a base in water as solvent, thereby forming hydrogen and a by-product (C1); wherein said phosphorous based catalyst is as defined in claim 1; and ii) recovering the obtained hydrogen.
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