An anti-mold film assembly has an absorptive sheet, a metallic coating and two first films. The absorptive sheet absorbs vaporizable ingredients and has a first side and a second side opposite to the first side of the absorptive sheet. The metallic coating is connected with the first side of the absorptive sheet and has a surface opposite to the absorptive sheet. The first films are ventilative and are respectively connected with the second side of the absorptive sheet and the surface of the metallic coating. Because the metallic coating is capable of drawing sulfhydryl groups of enzyme proteins contained in bacteria and killing the bacteria, the antibiotic effect of the anti-mold film assembly is greatly enhanced.