Described herein are solar modules including spectral concentrators. In one embodiment, a solar module includes an active layer including a set of photovoltaic cells. The solar module also includes a spectral concentrator optically coupled to the active layer and including a luminescent material that exhibits photoluminescence in response to incident solar radiation. The photoluminescence has: (a) a quantum efficiency of at least 30 percent; (b) a spectral width no greater than 100 nm at Full Width at Half Maximum; and (c) a peak emission wavelength in the near infrared range.