Invention Grant
US08686211B2 Process for preparing ethylene and/or propylene and a butadiene-enriched product 失效
制备乙烯和/或丙烯的方法和富含丁二烯的产物

  • Patent Title: Process for preparing ethylene and/or propylene and a butadiene-enriched product
  • Patent Title (中): 制备乙烯和/或丙烯的方法和富含丁二烯的产物
  • Application No.: US13606348
    Application Date: 2012-09-07
  • Publication No.: US08686211B2
    Publication Date: 2014-04-01
  • Inventor: Jeroen Van Westrenen
  • Applicant: Jeroen Van Westrenen
  • Applicant Address: US TX Houston
  • Assignee: Shell Oil Company
  • Current Assignee: Shell Oil Company
  • Current Assignee Address: US TX Houston
  • Priority: EP11180345 20110907
  • Main IPC: C07C2/00
  • IPC: C07C2/00
Process for preparing ethylene and/or propylene and a butadiene-enriched product
Abstract:
The present invention provides a process for preparing ethylene and propylene and a butadiene-enriched product, comprising the steps of: a) providing a C4 hydrocarbon stream, comprising iso-olefins and butadiene. b) subjecting the C4 hydrocarbon stream to an etherification process, wherein the iso-olefins are converted with methanol and/or ethanol to an tert-alkyl ether in the presence of a catalyst, wherein the molar ratio of alcohol to iso-olefin is maintained above 1, and retrieving an etherification product stream; c) separating the etherification product stream into an ether-enriched stream and a butadiene-enriched product; d) converting the tert-alkyl ether in the ether-enriched stream to ethylene and/or propylene by contacting least part of the ether-enriched stream with a molecular sieve-comprising catalyst at a temperature in the range of from 350 to 1000° C. and retrieving an olefinic product comprising ethylene and/or propylene.
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