A synchronization method for impulse system ultra-wideband takes frame as basic unit for data transmission, each frame is divided into a preamble symbol part and a data part, wherein the preamble symbol part sends a known impulse sequence for channel estimation and synchronization; the data part takes the information to be transmitted; the preamble symbol part is divided into two parts of a positive and negative impulse sequence, which includes odd impulses with alternant positive and negative polarities, and a same direction impulse sequence, which is composed of impulses with same polarity and is the same as the polarity of the last impulse in the positive and negative impulse sequence. The method provides such advantages as high synchronization precision, small storage space, and capability of immediately finding out the synchronization position etc., and provides an important value for the development of the impulse system ultra-wideband wireless communication technique.