Invention Grant
US08697808B2 Process for making ethylene polymer blends with controlled long-chain branching
有权
制备具有受控长链支化的乙烯聚合物共混物的方法
- Patent Title: Process for making ethylene polymer blends with controlled long-chain branching
- Patent Title (中): 制备具有受控长链支化的乙烯聚合物共混物的方法
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Application No.: US12941149Application Date: 2010-11-08
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Publication No.: US08697808B2Publication Date: 2014-04-15
- Inventor: Michael W. Lynch , Kenneth J. Klug
- Applicant: Michael W. Lynch , Kenneth J. Klug
- Applicant Address: US TX Houston
- Assignee: Equistar Chemicals, LP
- Current Assignee: Equistar Chemicals, LP
- Current Assignee Address: US TX Houston
- Main IPC: C08L23/04
- IPC: C08L23/04 ; C08L23/06

Abstract:
A high-temperature solution process for making an ethylene polymer blend having a controlled degree of long-chain branching is disclosed. Ethylene is polymerized in the presence of a first Ziegler-Natta catalyst comprising titanium, magnesium, and aluminum in the absence of hydrogen to produce a first ethylene polymer component having substantial long-chain branching. A second ethylene polymer component having little or no long-chain branching is also prepared. Both polymerizations are performed at a temperature from 140° C. to 250° C. The first and second ethylene polymer components are combined to give a polymer blend. The degree of long-chain branching in the blend is controlled by adjusting the relative amounts of the first and second ethylene polymer components. The invention enables the preparation of valuable products having a pre-determined degree of long-chain branching using readily available Zeigler-Natta catalysts, commercially practiced techniques, and conventional equipment.
Public/Granted literature
- US20120116022A1 PROCESS FOR MAKING ETHYLENE POLYMER BLENDS WITH CONTROLLED LONG-CHAIN BRANCHING Public/Granted day:2012-05-10
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