Invention Grant
US08709254B2 Hybrid silica membrane for water removal from lower alcohols and hydrogen separation 有权
混合二氧化硅膜用于从低级醇中除去水分和氢气分离

Hybrid silica membrane for water removal from lower alcohols and hydrogen separation
Abstract:
A microporous organic-inorganic hybrid membrane based on silica of the invention has an average pore diameter of less than 0.6 nm, and comprises bridging organosilane moieties of the formula ≡O1.5Si—CHR—SiO1.5≡ or ≡O1.5Si—CH(CH3)—SiO1.5≡. The membrane can be used in the separation of hydrogen from mixtures comprising hydrogen and CH4, CO2, CO, N2, and the like, and in the separation of water from alcohols having 1-3 carbon atoms, optionally in the presence of an inorganic or organic acid.
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