An exhaust diagnostic control system comprises a test enabling module, an exhaust gas temperature management module in communication with the test enabling module, and a component management module configured for executing a test for determining a reduction efficiency associated with the after-treatment component. The test enabling module is configured for assessing a reliability of an estimated level of reductant load on an after-treatment component, and, based on the reliability, selectively facilitating disablement of a subsequent test for determining an efficiency of NOx reduction in the after-treatment component. The exhaust gas temperature management module is configured for selectively adjusting a temperature of the after-treatment component to a predetermined temperature range using intrusive exhaust gas temperature management. The test for determining reduction efficiency comprises determining a NOx reduction efficiency of the after-treatment component.