A coaxial molecular stack (10) for transferring photocurrent generation in a device such as a solar cell (14) is disclosed. The device comprises a plurality of macrocyclic π-conjugated planar molecules stackable through columnar self assembly to form a stack (10) having an axial channel (26) with an outer p-channel (22) of the nano-composite coaxial molecular stack (10). A plurality of C60 molecules are positioned coaxially within the axial channel of the stack (10) to form an inner n-channel (24) that forms a bulk heterojunction with the p-channel (22) to provide charge transport of photocurrent through the nano-composite coaxial molecular stack (10). A plurality of the stacks (16) are oriented orthogonally between first (18) and second electrodes (20) to form the device (14).