Invention Grant
- Patent Title: Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof
- Patent Title (中): 使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸,酯和盐的方法及其用途
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Application No.: US13132153Application Date: 2009-10-06
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Publication No.: US08735476B2Publication Date: 2014-05-27
- Inventor: Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
- Applicant: Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
- Applicant Address: VG Tortola
- Assignee: Clariant Finance (BVI) Limited
- Current Assignee: Clariant Finance (BVI) Limited
- Current Assignee Address: VG Tortola
- Agent Anthony A. Bisulca
- Priority: DE102008060036 20081202; EPPCT/EP2009/007136 20091006
- International Application: PCT/EP2009/007136 WO 20091006
- International Announcement: WO2010/063342 WO 20100610
- Main IPC: C08K5/5313
- IPC: C08K5/5313

Abstract:
The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkylphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III).
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