Invention Grant
US08735476B2 Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof 有权
使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸,酯和盐的方法及其用途

  • Patent Title: Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof
  • Patent Title (中): 使用羧酸的乙烯基酯制备单羧基官能化的二烷基次膦酸,酯和盐的方法及其用途
  • Application No.: US13132153
    Application Date: 2009-10-06
  • Publication No.: US08735476B2
    Publication Date: 2014-05-27
  • Inventor: Michael HillMathias DietzWerner KrauseMartin Sicken
  • Applicant: Michael HillMathias DietzWerner KrauseMartin Sicken
  • Applicant Address: VG Tortola
  • Assignee: Clariant Finance (BVI) Limited
  • Current Assignee: Clariant Finance (BVI) Limited
  • Current Assignee Address: VG Tortola
  • Agent Anthony A. Bisulca
  • Priority: DE102008060036 20081202; EPPCT/EP2009/007136 20091006
  • International Application: PCT/EP2009/007136 WO 20091006
  • International Announcement: WO2010/063342 WO 20100610
  • Main IPC: C08K5/5313
  • IPC: C08K5/5313
Method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid and the use thereof
Abstract:
The invention relates to a method for producing mono-carboxy-functionalized dialkylphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkylphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III).
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