Invention Grant
- Patent Title: Method for producing dialkylphosphinic acids and esters and salts thereof by means of acrylnitriles and use thereof
- Patent Title (中): 通过丙烯腈生产二烷基次膦酸及其酯及其盐的方法及其用途
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Application No.: US13127069Application Date: 2009-10-06
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Publication No.: US08735477B2Publication Date: 2014-05-27
- Inventor: Michael Hill , Werner Krause , Martin Sicken
- Applicant: Michael Hill , Werner Krause , Martin Sicken
- Applicant Address: VG Tortola
- Assignee: Clariant Finance (BVI) Limited
- Current Assignee: Clariant Finance (BVI) Limited
- Current Assignee Address: VG Tortola
- Agent Anthony A. Bisulca
- Priority: DE102008056342 20081107
- International Application: PCT/EP2009/007131 WO 20091006
- International Announcement: WO2010/051891 WO 20100514
- Main IPC: C08K5/5313
- IPC: C08K5/5313

Abstract:
The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (H) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with compounds of formula (V) to yield mono-functionalized dialkylphosphinic acid derivatives (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivatives (VI) are reacted to yield a mono-carboxyfunctionalized diakylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X and Y are the same or different and stand independently of each for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates, and catalyst C is an acid or a base.
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