Invention Grant
- Patent Title: Functionalized high vinyl terminated propylene based oligomers
- Patent Title (中): 官能化高乙烯基封端的丙烯基低聚物
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Application No.: US13752998Application Date: 2013-01-29
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Publication No.: US08735502B2Publication Date: 2014-05-27
- Inventor: Patrick Brant , Donna J. Crowther
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Houston
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Houston
- Agent Kevin M. Faulkner; Catherine L. Bell
- Main IPC: C08F8/00
- IPC: C08F8/00 ; C08F8/46 ; C08F210/06 ; C08F110/06 ; C08F10/06

Abstract:
This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94 (mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g/mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g/mmol Hf (or Zr)/hour.
Public/Granted literature
- US20130137830A1 Functionalized High Vinyl Terminated Propylene Based Oligomers Public/Granted day:2013-05-30
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