Invention Grant
US08735522B2 Gold-polymer nanostructure-immobilized scandium catalyst and its use
有权
金聚合物纳米结构固定钪催化剂及其用途
- Patent Title: Gold-polymer nanostructure-immobilized scandium catalyst and its use
- Patent Title (中): 金聚合物纳米结构固定钪催化剂及其用途
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Application No.: US13580312Application Date: 2011-02-16
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Publication No.: US08735522B2Publication Date: 2014-05-27
- Inventor: Shu Kobayashi , Hiroyuki Miyamura
- Applicant: Shu Kobayashi , Hiroyuki Miyamura
- Applicant Address: JP Saitama
- Assignee: Japan Science and Technology Agency
- Current Assignee: Japan Science and Technology Agency
- Current Assignee Address: JP Saitama
- Agency: Jenkins, Wilson, Taylor & Hunt, P.A.
- Priority: JP2010-051987 20100309
- International Application: PCT/JP2011/053199 WO 20110216
- International Announcement: WO2011/111482 WO 20110915
- Main IPC: C08F12/30
- IPC: C08F12/30 ; C08K3/10

Abstract:
The present invention provides a Scandium catalyst that can be used in water or water-soluble organic solvent with no leaching of Scandium. Provided is a gold-polymer nanostructure-immobilized Scandium catalyst, which is formed by preparing, in liquid phase, a mixture comprising gold clusters with from 1 to 50 nm of diameter, disulfide monomer, sulfonic acid salt of disulfide and Lewis acid metal compound represented by ScY3, wherein Y is OSO2CF3 etc., and polymerizing the mixture in the presence of a radical polymerization initiator, wherein the disulfide monomer is represented by the formula below: CH2═CH—R1—S—S—R1—CH═CH2 wherein R1 represents a divalent hydrocarbon, which may contain an ether bond, and the sulfonic acid salt of disulfide is represented by the formula below: MO3S—R2—S—S—R2—SO3M wherein R2 represents a divalent hydrocarbon, which may contain an ether bond, and M represents an alkali metal. This catalyst is useful as a catalyst for aldol reactions, cyanolation reactions, allylation reactions, Michael reactions, Mannich reactions, Diels Alder reactions and Friedel Crafts reactions in water or water-soluble organic solvent.
Public/Granted literature
- US20130059999A1 GOLD-POLYMER NANOSTRUCTURE-IMMOBILIZED SCANDIUM CATALYST AND ITS USE Public/Granted day:2013-03-07
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