Optical compensation films and a method for reducing dark-state light leakage of vertical alignment liquid crystal displays are disclosed. The light path difference (LCΔND) is in a range of 324.3-342.8 nm, and the pretilt angle is in a range of 85 to 90 degrees when measured at a wavelength of 550 nm. Wherein an in-plain retardation value Ro of the biaxial compensation film is in the range of 48-84 nm, an out-of-plain retardation value Rth of the biaxial compensation film is in the range of 160-280 nm, and a retardation value Rth of the TAC compensation film is within a range between Y1 and Y2. The compensation structure with single layer of biaxial compensation film not only can reduce the dark-state light leakage, but also can increase the contrastness and the resolution in the wide viewing angle.