The present invention provides a liquid crystal panel and an alignment film thereof, and the alignment film is made of a modified polyimide which has conjugated double bond at side chain. Resistance value of the alignment film is less than the resistance value of a liquid crystal material of the liquid crystal panel by properties of the conjugated double bond that can reduce the resistance value of a prior art polyimide. In addition, improving the imidization ratio of a modified polyimide alignment film is important. The present invention is conducted the charged ion from liquid crystal layer to the alignment film by the conjugated double bond of the modified polyimide at the side chain to prevent the increase in the ion density of the liquid crystal in part of this area, and improve the problem of image sticking.