Invention Grant
- Patent Title: Acrolein manufacturing method and acrylic acid manufacturing method
- Patent Title (中): 丙烯醛制造方法和丙烯酸制造方法
-
Application No.: US12996335Application Date: 2009-06-04
-
Publication No.: US08742169B2Publication Date: 2014-06-03
- Inventor: Takanori Aoki , Masayuki Yoshimura
- Applicant: Takanori Aoki , Masayuki Yoshimura
- Applicant Address: JP Tokyo
- Assignee: Showa Denko K.K.
- Current Assignee: Showa Denko K.K.
- Current Assignee Address: JP Tokyo
- Agency: Sughrue Mion, PLLC
- Priority: JP2008-148095 20080605
- International Application: PCT/JP2009/060216 WO 20090604
- International Announcement: WO2009/148105 WO 20091210
- Main IPC: C07C51/16
- IPC: C07C51/16 ; C07C45/00

Abstract:
The present invention relates to a method for producing acrolein, comprising step (1) of subjecting glycerol to dehydration reaction in the presence of a copper compound and a compound containing a heteroatom; step (2) of recovering acrolein generated in the dehydration reaction step (1); step (3) of recovering part or all of the copper compound which remained after the recovery of acrolein; step (4) of treating part or all of the recovered copper compound with at least one member selected from a group consisting of an oxidizing agent and acid; and step (5) of returning part or all of the copper compound treated in the above step to step (1); and a method for producing acrylic acid, comprising reacting acrolein obtained by the above method with molecular oxygen. The production method of the present invention enables efficient production of acrolein and acrylic acid from glycerol contained in plant oil and animal fats derived from carbon dioxide in air without depending on the oxidation of propylene derived from fossil resources.
Public/Granted literature
- US20110087050A1 ACROLEIN MANUFACTURING METHOD AND ACRYLIC ACID MANUFACTURING METHOD Public/Granted day:2011-04-14
Information query