A motor stator with heat dissipation structure for fan includes a silicon steel plate assembly having a plurality of magnetic-pole columns, on each of which at least one winding is wound, and a space is defined between any two adjacent magnetic-pole columns; a covering being a heat-conducting plastic material filled in the spaces while covering the silicon steel plate assembly and the windings; and a plurality of heat pipes being extended into or through the covering filled in the spaces, so that heat produced by the silicon steel plate assembly and the windings during operation thereof can be transferred to the covering, and the heat pipes can absorb the heat from the covering and dissipate the absorbed heat into ambient air. Therefore, the silicon steel plate assembly and the windings can have lowered temperature and the cooling fan can have upgraded heat dissipation characteristic.