A method for selectively removing arsenic from a sulphide material containing arsenic by conducting a leaching step that includes contacting the material with a leaching solution that leaches arsenic from the material to form a pregnant liquor containing dissolved arsenic and a solid of a sulphide material of reduced arsenic content, and subsequently separating the solid from the pregnant liquor. The fresh leaching solution that is provided to the leaching step is an alkaline solution having a sulphide-containing compound present in an amount of from 0 to 1.0 times the amount of sulphur containing compound required to react with the arsenic present in the material.