A solar light-control module includes a light-propagation chamber, a plurality of micro structures, a refractive media, and at least one solar cell. The light-propagation chamber has a first face, a second face and at least one side surface. Ambient light is incident to the first face to enter the solar light-control module. The micro structures are disposed on the second face to deflect the ambient light and guide the ambient light to a predetermined area of the light-propagation chamber. The refractive media is disposed between the second face of the light-propagation chamber and the micro structures, and the solar cell is disposed on the predetermined area.