Invention Grant
US08846858B2 Method for alcoholysis of polycarbonate compositions containing flame retardant or acrylonitrile-butadiene-styrene
有权
含有阻燃剂或丙烯腈 - 丁二烯 - 苯乙烯的聚碳酸酯组合物的醇解方法
- Patent Title: Method for alcoholysis of polycarbonate compositions containing flame retardant or acrylonitrile-butadiene-styrene
- Patent Title (中): 含有阻燃剂或丙烯腈 - 丁二烯 - 苯乙烯的聚碳酸酯组合物的醇解方法
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Application No.: US13723425Application Date: 2012-12-21
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Publication No.: US08846858B2Publication Date: 2014-09-30
- Inventor: Philip Wesley Bell , Alexander Stanislaus , Venkata Ramanarayanan Ganapathy Bhotla , Rathinam Jothi Mahalingam
- Applicant: Saudi Basic Industries Corporation
- Applicant Address: SA Riyadh
- Assignee: Saudi Basic Industries Corporation
- Current Assignee: Saudi Basic Industries Corporation
- Current Assignee Address: SA Riyadh
- Agency: Cantor Colburn LLP
- Main IPC: C08G64/00
- IPC: C08G64/00 ; C08G64/06 ; C08G64/30 ; C07C37/50 ; C07C68/06 ; C08G64/40 ; C08G63/02

Abstract:
The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70° C. to 200° C., and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.
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