Invention Grant
US08846858B2 Method for alcoholysis of polycarbonate compositions containing flame retardant or acrylonitrile-butadiene-styrene 有权
含有阻燃剂或丙烯腈 - 丁二烯 - 苯乙烯的聚碳酸酯组合物的醇解方法

Method for alcoholysis of polycarbonate compositions containing flame retardant or acrylonitrile-butadiene-styrene
Abstract:
The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70° C. to 200° C., and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.
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