A method and a system for segmenting phonemes from voice signals. A method for accurately segmenting phonemes, in which a histogram showing a peak distribution corresponding to an order is formed by using a high order concept, and a boundary indicating a starting point and an ending point of each phoneme is determined by calculating a peak statistic based on the histogram. The phoneme segmentation method can remarkably reduce an amount of calculation, and has an advantage of being applied to sound signal systems which perform sound coding, sound recognition, sound synthesizing, sound reinforcement, etc.