Invention Grant
US08865848B2 Process for olefin polymerisation using group 4 metallocene as catalysts
有权
使用4族茂金属作为催化剂的烯烃聚合方法
- Patent Title: Process for olefin polymerisation using group 4 metallocene as catalysts
- Patent Title (中): 使用4族茂金属作为催化剂的烯烃聚合方法
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Application No.: US13806386Application Date: 2011-06-29
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Publication No.: US08865848B2Publication Date: 2014-10-21
- Inventor: Pascal Castro , Luigi Resconi , Lauri Huhtanen
- Applicant: Pascal Castro , Luigi Resconi , Lauri Huhtanen
- Applicant Address: AT Vienna
- Assignee: Borealis AG
- Current Assignee: Borealis AG
- Current Assignee Address: AT Vienna
- Agency: Meunier Carlin & Curfman, LLC
- Priority: EP10168152 20100701
- International Application: PCT/EP2011/060920 WO 20110629
- International Announcement: WO2012/001051 WO 20120105
- Main IPC: C08F4/6592
- IPC: C08F4/6592 ; C08F4/642 ; C08F210/06 ; B01J31/22 ; C08F210/16 ; C08F4/659

Abstract:
A process for the preparation of a random propylene copolymer comprising polymerizing propylene and at least one C2-10 alpha olefin (especially ethylene) in the presence of a catalyst; wherein said catalyst comprises: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and (ii) a cocatalyst comprising an organometallic compound of a Group 13 metal.
Public/Granted literature
- US20130217845A1 PROCESS FOR OLEFIN POLYMERISATION USING GROUP 4 METALLOCENE AS CATALYSTS Public/Granted day:2013-08-22
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