Invention Grant
US08877989B2 Dehydration process of hydrofluorocarbon or hydrochlorofluorocarbon and production method of 1,3,3,3-tetrafluoropropene using the dehydration process
有权
使用脱水方法制备1,3,3,3-四氟丙烯的氢氟碳化合物或氢氯氟烃的脱水方法
- Patent Title: Dehydration process of hydrofluorocarbon or hydrochlorofluorocarbon and production method of 1,3,3,3-tetrafluoropropene using the dehydration process
- Patent Title (中): 使用脱水方法制备1,3,3,3-四氟丙烯的氢氟碳化合物或氢氯氟烃的脱水方法
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Application No.: US13188884Application Date: 2011-07-22
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Publication No.: US08877989B2Publication Date: 2014-11-04
- Inventor: Yoshio Nishiguchi , Yasuo Hibino
- Applicant: Yoshio Nishiguchi , Yasuo Hibino
- Applicant Address: JP Ube-shi
- Assignee: Central Glass Company, Limited
- Current Assignee: Central Glass Company, Limited
- Current Assignee Address: JP Ube-shi
- Agency: Crowell & Moring LLP
- Priority: JP2010-205473 20100914; JP2011-145451 20110630
- Main IPC: C07C17/08
- IPC: C07C17/08 ; C07C17/25 ; C07C17/383 ; C07C17/20 ; C07C17/21 ; C07C17/38

Abstract:
A process for dehydrating a hydrofluorocarbon or hydrochlorofluorocarbon, which can be done by simple equipment, and a continuous process of producing 1,3,3,3-tetrafluoropropene using the dehydration process. The dehydration process includes cooling the hydrofluorocarbon or hydrochlorofluorocarbon in gaseous form containing water with a heat exchanger, thereby condensing and liquefying the hydrofluorocarbon or hydrochlorofluorocarbon while freezing and solidifying the water. The 1,3,3,3-tetrafluoropropene production method includes a first step for fluorinating 1-chloro-3,3,3-trifluoropropene with hydrogen fluoride to obtain a mixture of 1,3,3,3-tetrafluoropropene, unreacted 1-chloro-3,3,3-trifluoropropene, hydrogen fluoride, hydrogen chloride and by-products, or dehydrofluorinating 1,1,1,3,3-pentafluoropropane to obtain a mixture of 1,3,3,3-tetrafluoropropene, unreacted 1,1,1,3,3-pentafluoropropane and by-products, a second step for removing acidic components, a third step for dehydrating the 1,3,3,3-tetrafluoropropene by the above dehydration process, and a fourth step for purifying the 1,3,3,3-tetrafluoropropene by distillation.
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