A system and method have a choke in fluid communication with a rotating control device. The choke controls flow of drilling mud from the rotating control device to a gas separator during a controlled pressure drilling operation, such as managed pressure drilling (MPD) or underbalanced drilling (UBD). A probe is in fluid communication with the drilling mud between the choke and the gas separator. During operations, the probe evaluates gas in the drilling mud from the well passing from the choke to the gas separator.