A high-strength disengagement prevention pintle veneer tie and anchoring system employing the same is disclosed. The high-strength veneer tie utilizes modified compressed wire formatives formed from a wire formative construct that is cold-worked, with the resultant body having substantially semicircular edges and flat surfaces therebetween. The edges are aligned to receive compressive forces transmitted from the outer wythe. The veneer tie hereof, when part of the anchoring system, interengages with wall anchor and is dimensioned to preclude veneer tie movement and pullout through the use of the U-shaped securement portions. The veneer tie is installed within the wall anchor through a swinging motion, in either an over and through or under and through the anchor installation, fully securing the veneer tie within the anchor and providing flexibility during installation.