Invention Grant
US08926736B2 Reducible porous crystalline hybrid solid for the separation of mixtures of molecules having different degrees and/or a different number of unsaturations
有权
用于分离具有不同程度和/或不同数目的不饱和度的分子的混合物的可还原的多孔结晶杂化固体
- Patent Title: Reducible porous crystalline hybrid solid for the separation of mixtures of molecules having different degrees and/or a different number of unsaturations
- Patent Title (中): 用于分离具有不同程度和/或不同数目的不饱和度的分子的混合物的可还原的多孔结晶杂化固体
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Application No.: US12996325Application Date: 2009-06-11
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Publication No.: US08926736B2Publication Date: 2015-01-06
- Inventor: Christian Serre , Alexandre Vimont , Philip Llewellyn , Jong-San Chang , Patricia Horcajada-Cortes , Gérard Ferey , Marco Daturi , Young-Kyu Hwang
- Applicant: Christian Serre , Alexandre Vimont , Philip Llewellyn , Jong-San Chang , Patricia Horcajada-Cortes , Gérard Ferey , Marco Daturi , Young-Kyu Hwang
- Applicant Address: FR Paris FR Caen FR Versailles KR Daejeon
- Assignee: Centre National de la Recherche Scientifique -CNRS-,Universite de Caen-Basse Normandie,Universite de Versailles—Saint Quentin en Yvelines,Korea Research Institute of Chemical & Technology (KRICT)
- Current Assignee: Centre National de la Recherche Scientifique -CNRS-,Universite de Caen-Basse Normandie,Universite de Versailles—Saint Quentin en Yvelines,Korea Research Institute of Chemical & Technology (KRICT)
- Current Assignee Address: FR Paris FR Caen FR Versailles KR Daejeon
- Agency: Arent Fox LLP
- Priority: FR0803245 20080611
- International Application: PCT/FR2009/000699 WO 20090611
- International Announcement: WO2010/000975 WO 20100107
- Main IPC: C07C7/13
- IPC: C07C7/13 ; B01D53/04
Abstract:
The present invention relates to reducible porous crystalline solids, constituted of a metal-organic framework (MOF), for the separation of mixtures of molecules having different unsaturation degrees and/or a different number of unsaturations with a selectivity that can be adjusted by controlling the reduction of the MOF. The MOF solids of the present invention, after reduction, have a strong affinity for molecules containing at least one unsaturation. They can be used in various separation processes, especially those relating to hydrocarbons.
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