Invention Grant
- Patent Title: Tertiary amine preparation process
- Patent Title (中): 叔胺制备方法
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Application No.: US13976365Application Date: 2011-12-27
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Publication No.: US08927772B2Publication Date: 2015-01-06
- Inventor: Masahiko Watanabe , Gosuke Tateno , Hirofumi Mizukoshi
- Applicant: Masahiko Watanabe , Gosuke Tateno , Hirofumi Mizukoshi
- Applicant Address: JP Tokyo
- Assignee: Kao Corporation
- Current Assignee: Kao Corporation
- Current Assignee Address: JP Tokyo
- Agency: Birch, Stewart, Kolasch & Birch, LLP
- Priority: JP2010-291233 20101227; JP2011-286771 20111227
- International Application: PCT/JP2011/080344 WO 20111227
- International Announcement: WO2012/091071 WO 20120705
- Main IPC: C07C209/16
- IPC: C07C209/16 ; C01B3/58

Abstract:
The present invention relates to a process for producing a tertiary amine, including the following steps (1) and (2):Step (1); introducing an alcohol having 1 to 36 carbon atoms and a raw amine represented by the following general formula (I) into a first reaction vessel to react with each other in the presence of a catalyst and hydrogen, and then continuing the reaction while discharging water produced in the reaction and a hydrogen-containing gas out of a reaction system in the first reaction vessel: R1R2NH (I) wherein R1 and R2 are each independently a hydrogen atom or a hydrocarbon group having 1 to 36 carbon atoms; and Step (2): introducing the hydrogen-containing gas discharged from the first reaction vessel into a second reaction vessel to reduce an amount of carbon monoxide contained in the hydrogen-containing gas, and then introducing a part or whole of the hydrogen-containing gas into the first reaction vessel.
Public/Granted literature
- US20130289309A1 TERTIARY AMINE PREPARATION PROCESS Public/Granted day:2013-10-31
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