The disclosure provides in one embodiment a method of applying a high temperature hybridized molecular functional group adhesion barrier coating to a surface of a structure. The method includes providing a structure having at least one surface to be bonded, preparing the at least one surface to expose active reactive surface sites, providing one or more liquid or solid phase chemical derivatization compounds, applying heat to the one or more liquid or solid phase chemical derivatization compounds to vaporize the one or more liquid or solid chemical derivatization compounds, depositing the one or more vaporized chemical derivatization compounds on the prepared surface to form a derivatized composite surface having hybridized molecular functional groups, and heat curing the derivatized composite surface to form a high temperature hybridized molecular functional group adhesion barrier coating.